PHTHALOCYANINES CONTAINING RESORCINARENE CAVITANDS; SYNTHESIS AND HEAVY METAL ION EXTRACTION PROPERTIES

Kantar C.

REVUE ROUMAINE DE CHIMIE, cilt.64, sa.4, ss.361-367, 2019 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 64 Sayı: 4
  • Basım Tarihi: 2019
  • Doi Numarası: 10.33224/rrch/2019.64.4.09
  • Dergi Adı: REVUE ROUMAINE DE CHIMIE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.361-367
  • Anahtar Kelimeler: phthalocyanine, resorcinarene, heavy metal ion extraction, liquid-liquid extraction, cavitand, COMPLEXATION
  • Recep Tayyip Erdoğan Üniversitesi Adresli: Evet

Özet

There are several studies about phthalocyanines containing resorcin[4]arene groups at literature. However, their heavy metal ion extraction properties are unknown. Therefore, the novel phthalocyanines containing tetra and octa resorcin[4]arene cavitands were synthesized and investigated extraction properties for some environmentaly important heavy metal ions. The structures were characterized by elemental analysis, H-1 NMR, C-13 NMR, UV/vis and FT-IR spectroscopy techniques. The extraction capacities were analyzed through liquid-liquid extraction method. The novel phthalocyanine compounds TP5ZnPc and TP6ZnPc seem to be proper for the removal of heavy metal cations.